Interactions des alcynes avec les complexes carbéniques du tungstène portant une double liaison carbone— carbone: Accès aux dérivés bicyclo[4,1,0]. Download Citation on ResearchGate | Réaction des halogenures de titane(IV) avec les alcynes: Formation d’halogénoalcènes | The behaviour of some mono-. Download Citation on ResearchGate | Action du chlorure de fer(III) sur les alcynes: Reduction du fer(III) en fer(II) et formation d’un chloro-alcene | The behaviour.

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All items in eScholarship McGill are protected by copyright with all rights reserved unless otherwise indicated. In addition, the reaction proceeds with high diastereo- and regioselectivity. Access to the PDF text. Alcnyes homepage About open access About eScholarship Report a copyright concern Deposit your publication Prepare your thesis Ask a librarian Feedback.

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CHIM 263 – Chimie organique II

The University’s open access institutional repository: Deposit your publication Prepare your thesis Ask a librarian Feedback. In conjunction with Prof. In addition, the results of the theoretical investigation of Chapter 2 are exploited to show how changes in the phosphorus substituents can be used to fine tune regioselectivity of alkyne cycloadditions without modifying the substituents on the final product. Similarly, the rational on regioselectivity also allows the prediction of regioselectivity for a wide scope of alkynes.

Comparison of three enoate reductases and their potential use for biotransformations. Method for producing distillate from a hydrocarbon feed, lss alcohol condensation.


Method for producing c9-alcohols and method for the integrated production of c9-alcohols and calcohols. Propargylic carboxylates lead to conjugated dienes by coupling of the diazoalkane carbene with the alkyne terminal carbon lss 1,2-shift of the carboxylate. Access to the full text of this article requires a subscription.

The owners of this website hereby guarantee to respect the legal confidentiality conditions, applicable in France, and not to disclose this data to third parties. Simple alkynes generate dienes via double diazoalkane carbene addition to the triple bond.

X-ray crystallographic studies demonstrate the significant role of the PR3 unit on the ground state structure of these dipoles and their reactivity. Previous Article Gecom-Concoord Country of ref document: Molecular characterization of genes of Pseudomonas sp. You may thus request that your data, should it be inaccurate, incomplete, unclear, outdated, not be used or stored, be corrected, lrs, updated or deleted. Epoxide hydrolases from yeasts and other sources: Enantioselective reduction of carbonyl compounds by whole-cell biotransformation, combining a formate dehydrogenase and a R -specific slcynes dehydrogenase.

EP Kind code of ref document: Malonyl-coenzyme A reductase in the modified 3-hydroxypropionate cycle for autotrophic carbon fixation in archaeal Metallosphaera and Sulfolobus spp. Contact Help Who are we? While each of the dipoles are established to participate in 1,3-dipolar cycloaddition reactions, until now, no general rules regarding the factors that control regioselectivity have been described.

Different phosphites and phosphonites are tested for their ability to mediate intramolecular cycloaddition with alkenes, and optimum results are obtained with 2-catechyl PPh. Enzymatic processes for the production of 4-substituted 3-hydroxybutyric acid derivatives and vicinal cyano, hydroxy substituted carboxylic acid esters. US USA1 en Applications of new phosphorus-based 1,3-dipolar cycloaddition reagents in nitrogen heterocycle synthesis.


Double catalytic addition of diazo compounds to alkynes: Importantly, these 1,3-dipoles display divergent regioselectivity, which can be exploited to synthesize a variety of pyrroles with high selectivity through the use of the appropriate reactant. Methods of refining and producing dibasic esters and acids from natural oil feedstocks.

Aryne — Wikipédia

Catalysis, Ruthenium, Diazo compounds, Carbene, Alkynes. Journal page Archives Contents list. A unique role in the addition of diazoalkane carbene to alkynes.

Outline Masquer le plan. Record 1 of 1. Enynes with terminal triple bond lead to alkenyl bicyclo[x. These 1,3-dipoles have been previously demonstrated to be accessible in a one-pot reaction of imines, acid chlorides and organophosphorus reagents, and participate in 1,3-dipolar cycloaddition reactions.

Catalytic addition of diazoalkane carbene to propargylic compounds: Personal information regarding our website’s visitors, including their identity, is confidential. Library homepage About open alcyjes About eScholarship Report a copyright concern.

Polycyclic 2-pyrrolines are generated in rapid cycloaddition reactions, in a modular fashion from easily accessible starting materials: As per the Law relating to information storage and personal integrity, lfs have the right to oppose art 26 of that lawaccess art 34 of that law and rectify art 36 of that law your personal data. Access to the text HTML.